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Continuous biodiesel production using ultrasound clamp on tubular reactor

机译:在管式反应器上使用超声钳连续生产生物柴油

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摘要

Biodiesel is an alternative fuel to be substituted with diesel fuel for diesel engines. It consists of alkyl monoesters of fatty acid from vegetable oil or animal fats and it is an alternative feedstock that can be converted into biodiesel at lower cost. A fast and low cost method to convert vegetable oil into biodiesel through the use of ultrasound clamp assistance has been investigated. The approach of this production is by using the ultrasound clamp to enhance the immiscible liquids between the vegetable oil and alcohol to emulsify together in a short period of time comparing to conventional stirring method which takes longer time for esters to form. The ultrasound causes the rapid movement of fluid hence creating cavitation where the liquids breaks down and cavitation bubbles created. The optimum results for biodiesel production using ultrasound clamp assisted on the tubular reactor is 3 minutes with the conversion of esters 90 % compared to the previous pilot plant unit which achieve 98 % of esters conversion within 5 minutes. The newly fabricated small pilot plant has indeed able to achieve the esters conversion with the presence of methanol to oil molar ratio of 12:1, catalyst concentration of 1,25 %wt and reaction temperature of 64°C. The newly fabricated small pilot plant has been developed in this research to facilitate the transesterification process in producing biodiesel from vegetable oil.
机译:生物柴油是柴油发动机替代柴油的替代燃料。它由植物油或动物脂肪中的脂肪酸烷基单酯组成,是一种替代原料,可以以较低的成本转化为生物柴油。已经研究了通过使用超声钳辅助技术将植物油转化为生物柴油的快速,低成本方法。与常规搅拌方法相比,这种生产方法是通过使用超声波钳来增强植物油和醇之间的不混溶液体,从而在短时间内一起乳化,而传统的搅拌方法需要更长的时间才能形成酯。超声波引起流体的快速运动,从而在液体分解并形成空化气泡的地方形成空化。与之前的中试装置(在5分钟内实现98%的酯转化率)相比,使用在管式反应器上辅助的超声钳进行生物柴油生产的最佳结果为3分钟,酯的转化率为90%。在甲醇与油的摩尔比为12:1,催化剂浓度为1.25 wt%,反应温度为64°C的条件下,新建的小型中试装置确实能够实现酯转化。在这项研究中,已经开发出了新制造的小型中试装置,以促进酯交换反应从植物油生产生物柴油的过程。

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